Microstructural design of printed graphite electrodes for lithium-ion batteries

نویسندگان

چکیده

Performance properties of lithium-ion battery electrodes; capacity, rate and lifetime, are determined by the design coating composite microstructure. The internal pore structure electronic networks for high coat weight graphite electrodes manipulated through changes in ink rheological properties, an syringe dispensing printing process. a water-based, viscosity were optimised using secondary solvent requirements method. microstructure coat-weight produced from tape cast methods compared electrochemical performance evaluated. Cross sectional analysis slurry coatings showed improved component homogeneity, lower alignment with 0.1% to 10% increase solvent, corresponding change tortuosity 5.3–2.8. Improved cycle life is observed printed electrode containing embedded electrolyte channel. elucidated charge discharge, GITT PEIS measurements. conductivities, exchange currents diffusion coefficients deposited electrode. This digital deposition process manufacturing shows promise further optimisation long-life, energy density batteries.

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ژورنال

عنوان ژورنال: Materials & Design

سال: 2021

ISSN: ['1873-4197', '0264-1275']

DOI: https://doi.org/10.1016/j.matdes.2021.109720