Microstructural design of printed graphite electrodes for lithium-ion batteries
نویسندگان
چکیده
Performance properties of lithium-ion battery electrodes; capacity, rate and lifetime, are determined by the design coating composite microstructure. The internal pore structure electronic networks for high coat weight graphite electrodes manipulated through changes in ink rheological properties, an syringe dispensing printing process. a water-based, viscosity were optimised using secondary solvent requirements method. microstructure coat-weight produced from tape cast methods compared electrochemical performance evaluated. Cross sectional analysis slurry coatings showed improved component homogeneity, lower alignment with 0.1% to 10% increase solvent, corresponding change tortuosity 5.3–2.8. Improved cycle life is observed printed electrode containing embedded electrolyte channel. elucidated charge discharge, GITT PEIS measurements. conductivities, exchange currents diffusion coefficients deposited electrode. This digital deposition process manufacturing shows promise further optimisation long-life, energy density batteries.
منابع مشابه
Nanostructured Lithium-Aluminum Alloy Electrodes for Lithium-Ion Batteries
Electrodeposited aluminum films and template-synthesized aluminum nanorods are examined as negative electrodes for lithium-ion batteries. The lithium-aluminum alloying reaction is observed electrochemically with cyclic voltammetry and galvanostatic cycling in lithium half-cells. The electrodeposition reaction is shown to have high faradaic efficiency, and electrodeposited aluminum films reach t...
متن کاملIrreversible capacities of graphite anode for lithium-ion batteries
Electrochemical impedance spectroscopy (EIS) and in-situ intrinsic resistance measurements were applied to sandwiched disk graphite electrodes to investigate the mechanism of formation of irreversible capacity during initial galvanostatic or potentiostatic lithium intercalation into graphite in four different electrolyte formulations. The stability of the solid electrolyte interphase (SEI) film...
متن کاملCharge–discharge stability of graphite anodes for lithium-ion batteries
A graphite powder disk sandwiched between two nickel screens was used as a lithium-insertion working electrode. Electrochemical impedance spectroscopy (EIS), galvanostatic intermittent titration (GIT) using pulsed microcurrent, and in-situ intrinsic resistance measurements were used for the evaluation of kinetics and intrinsic (i.e. physical) resistance changes during charge–discharge cycling f...
متن کاملKinetic characteristics of mixed conductive electrodes for lithium ion batteries
The rate performances of four mixed conductive electrodes (Li4/3Ti5/3O4, LiFePO4, LiCoO2 and LiCo1/3Ni1/3Mn1/3O2) were investigated using alvanostatic charge/discharge, electrochemical impedance Spectroscopy (EIS) and galvanostatic intermittent titration (GITT). These four electrode aterials can be roughly divided into two groups according to the structure change during Li intercalation/extract...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Materials & Design
سال: 2021
ISSN: ['1873-4197', '0264-1275']
DOI: https://doi.org/10.1016/j.matdes.2021.109720